Enhanced electron transfer by dendritic architecture: Energy transfer and electron transfer in snowflake-shaped Zn porphyrin dendrimers

被引:31
作者
Kozaki, Masatoshi [1 ]
Akita, Kogen [1 ]
Okada, Keiji [1 ]
机构
[1] Osaka City Univ, Grad Sch Sci, Sumiyoshi Ku, Osaka 5588585, Japan
关键词
INTRAMOLECULAR ENERGY; TRANSDUCTION; MORPHOLOGY; MOLECULES;
D O I
10.1021/ol070245h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Photoinduced electron transfer was observed for the snowflake-shaped dendrimer with the Zn porphyrin core and anthraquinonyl terminals. Comparison of the electron-transfer efficiency of the dendrimer with the linear analogues indicates the advantage of the dendritic structure for the electron-transfer process.
引用
收藏
页码:1509 / 1512
页数:4
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