Control of the Helicity of Poly (phenylacetylene)s: From the Conformation of the Pendant to the Chirality of the Backbone

被引：78

作者：

Louzao, Iria ^{[1
]}

Seco, Jose M. ^{[1
]}

Quinoa, Emilio ^{[1
]}

Riguera, Ricardo ^{[1
]}

机构：

[1] Univ Santiago de Compostela, Dept Quim Organ, Fac Quim, Santiago De Compostela 15782, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 08期

关键词：

barium; helical structures; isomerization; polymers; solvent effects; ABSOLUTE-CONFIGURATION; MACROMOLECULAR HELICITY; CHAIN HELICITY; POLY(PHENYLACETYLENE); SENSE; POLYACETYLENE; COMPLEXATION; BARIUM(II); H-1-NMR; AMINES;

D O I：

10.1002/anie.200905222

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Helix sense selection: Tuning the conformational equilibrium of the pendants of poly(phenylacetylene)s allows selection of the helicity of the polymer in a reversible way. Complexation with appropriate metal cations (e.g. Ba2+) or changing the polarity of the solvent permits the reversible selection of the desired helix sense. A full picture of the mechanism explaining this phenomenon is presented. © 2010 Wiley-VCH Verlag GmbH &. Co. KGaA.

引用

页码：1430 / 1433

页数：4

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[2]

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[3]

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[4]

[Anonymous], FOLDAMERS