Hydrogen peroxide formation in the interaction of oxygen with boron-containing Pd catalysts prereduced by hydrazine in aqueous acidic medium containing bromide anions

被引：9

作者：

Choudhary, VR ^{[1
]}

Samanta, C ^{[1
]}

机构：

[1] Natl Chem Lab, Chem Engn & Proc Dev Div, Pune 411008, Maharashtra, India

来源：

CATALYSIS LETTERS | 2005年 / 99卷 / 1-2期

关键词：

boron-containing Pd catalysts; hydrogen peroxide; oxygen-catalyst interactions;

D O I：

10.1007/s10562-004-0779-z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Interaction of molecular oxygen with Pd/BPO4 or ZrO2 (or Al2O3, CeO2, TiO2) - B2O3 catalysts, prereduced by hydrazine hydrate, in an aqueous acidic (H2SO4 or H3PO4) reaction medium containing bromide ions leads to the formation of H2O2. However, in the absence of boron in the catalyst and also in the absence of acid and/or bromide ions in the reaction medium, almost no H2O2 is formed.

引用

页码：79 / 81

页数：3

共 12 条

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