Intermolecular interactions in nonorganic crystal engineering

被引：529

作者：

Braga, D

Grepioni, F

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[2] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2000年 / 33卷 / 09期

关键词：

D O I：

10.1021/ar990143u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The utilization of noncovalent interactions to construct molecular crystals is evaluated in the context of inorganic and organometallic crystal engineering. The attention is focused on hydrogen-bonding interactions involving metal complexes in which the metal atoms participate in the bonding either directly or as ancillary systems. The role of ionic charges is discussed. It is shown, inter alia, that reproducible and transferable crystal synthesis strategies based on charge-assisted hydrogen bonds can be devised to build periodical supermolecules.

引用

页码：601 / 608

页数：8

共 37 条

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