Organosilane effects on organotitanium-catalyzed styrene polymerization

被引：12

作者：

Amin, Smruti B. ^{[1
]}

Marks, Tobin J. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 12期

关键词：

D O I：

10.1021/om0700260

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Organosilane reagents are introduced into organotitanium-mediated styrene polymerizations to produce atactic polystyrene with high activities (up to 10(6) g polymer/(mol Ti.h)) and narrow polydispersities. Previously recognized CGCTiMe(2) systems having marginal styrene homopolymerization activity are shown to be up to 3 orders of magnitude more active for styrene homopolymerization upon addition of organosilane.

引用

页码：2960 / 2963

页数：4

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