Crystal tectonics: Chemical construction and self-organization beyond the unit cell

被引:38
作者
Mann, S [1 ]
Davis, SA [1 ]
Hall, SR [1 ]
Li, M [1 ]
Rhodes, KH [1 ]
Shenton, W [1 ]
Vaucher, S [1 ]
Zhang, BJ [1 ]
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 21期
关键词
D O I
10.1039/b004066p
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Crystal tectonics involves the chemical-based construction and self-assembly of organized materials from solid-state building blocks, such as inorganic nanoparticles. This Perspective describes, through a series of examples, how the architectural complexity of materials with higher-order structure can be controlled by organic templating, interparticle molecular recognition and mesophase transformation. It is shown how the coupling of synthesis and self-assembly over multiple length scales is leading to new horizons in the chemistry of organized matter.
引用
收藏
页码:3753 / 3763
页数:11
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