Cleavage of the Pt-S bond of thiolated terpyridine-platinum(II) complexes by copper(II) and zinc(II) ions in phosphate buffer

被引：11

作者：

Cheng, CC ^{[1
]}

Lu, YL ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 11529, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 02期

关键词：

D O I：

10.1039/a708152i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using the chelation of a triamine moiety and an S-bridged heterodinuclear unit, cleavage of the Pt-S bond in the thiolate-platinum complexes, [Pt(terpy)(BAT)](4+) and [Pt(terpy)(AET)](+) is induced by adding transition metals such as Cu2+ Or Zn2+ in phosphate buffer (pH 7-8) at room temp.

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页码：253 / 254

页数：2

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