Modelling and simulation of multicomponent nonlinear chromatography

被引：4

作者：

Zenhausern, R ^{[1
]}

Rippin, DWT ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Tech Chem Lab, CH-8092 Zurich, Switzerland

来源：

COMPUTERS & CHEMICAL ENGINEERING | 1998年 / 22卷 / 1-2期

关键词：

D O I：

10.1016/S0098-1354(96)00364-X

中图分类号：

TP39 [计算机的应用];

学科分类号：

081203 ; 0835 ;

摘要：

The equilibrium relationship between the stationary and the mobile phase plays a leading role in chromatography; especially for higher concentrations where the equilibrium relationship becomes nonlinear. Based on local equilibrium theory, a simple numerical algorithm is developed by considering the multicomponent nonlinear equilibrium relationship and its Jacobian matrix to quickly obtain a first prediction of the chromatographic separation without the need of providing mass transfer data. The impact of several favorable multicomponent equilibrium isotherms on chromatographic separations is studied: The multicomponent Langmuir isotherm, a polynomial and an exponential extension of the multicomponent Langmuir isotherm. (C) 1997 Elsevier Science Ltd.

引用

页码：259 / 281

页数：23

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