Metallacyclophanes formed by a tetrapyrazolyl ligand and copper(II) cation

被引:24
作者
Jouaiti, A [1 ]
Loï, M [1 ]
Hosseini, MW [1 ]
De Cian, AE [1 ]
机构
[1] Univ Strasbourg, Chim Coordinat Organ Lab, UMR CNRS 7513, F-67000 Strasbourg, France
关键词
D O I
10.1039/b006665f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Using a tetrakis(pyrazolyl)benzene ligand and CuCl2 or Cu(CF3SO3)(2) salts, binuclear metallamacrocycles of cyclophane type have been exclusively obtained; structural characterisation by X-ray on single-crystal reveals that in both cases, chloride or triflate anions are coordinated to Cu metal centres adopting a square pyramial coordination geometry.
引用
收藏
页码:2085 / 2086
页数:2
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