Surface states induced photoluminescence from Mn2+ doped CdS nanoparticles

被引:108
作者
Liu, SM
Liu, FQ
Guo, HQ
Zhang, ZH
Wang, ZG
机构
[1] Chinese Acad Sci, Inst Semicond, Lab Semicond Mat Sci, Beijing 100083, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
基金
中国国家自然科学基金;
关键词
nanostructure; chemical synthesis; optical properties; impurities in semiconductors;
D O I
10.1016/S0038-1098(00)00254-4
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Manganese doped CdS nanoparticles were synthesized in basic aqueous solution by using mercapto acetate as capping reagents. The nanoparticles were characterized by HRTEM, EPR, photoluminescence and optical absorption measurements. Out of our expectation, doping of Mn2+ ions altered the recombination paths in CdS nanoparticles markedly. The surface stares facilitated PL from Mn2+ doped CdS nanoparticles is reported. A complete suppression of the emission from surface states at room temperature when doping with Mn2+ ions has been observed for the first time. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:615 / 618
页数:4
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