New platforms integrating ethynyl-grafted modules for organogels and mesomorphic superstructures

被引：32

作者：

Camerel, F ^{[1
]}

Ulrich, G ^{[1
]}

Ziessel, R ^{[1
]}

机构：

[1] Univ Strasbourg, ECPM Strasbourg, CNRS, Chim Lab, F-67087 Strasbourg 02, France

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 23期

关键词：

D O I：

10.1021/ol048503n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A methyldiacylaminophenyl core substituted with gallic derivatives and alkynyl functions has been synthesized from 2,6-diamino-4-iodotoluene. By heating the iodo and ethynyl molecules, typical columnar mesophases are observed and the C-12 synthons bearing a protected terminal alkyne group gelified acetone, via the formation of interlocked fibers which are promoted by intermolecular hydrogen bonding.

引用

页码：4171 / 4174

页数：4

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