Indolophanetetrayne cobalt complexes via Nicholas reactions

被引:20
作者
Gibe, R [1 ]
Green, JR [1 ]
Davidson, G [1 ]
机构
[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada
关键词
D O I
10.1021/ol027564n
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHIC] Indole N-substituted diyne tetracobalt complexes (4) undergo a Lewis acid mediated dimerization-cyclization reaction through the indole 3-position to afford indolophanetetrayne cobalt complexes (7). Substitution of the indole fragment of (4) with a 3-methyl function allows analogous formation of indolophanetetrayne complex (9), linked through the indole 2-position.
引用
收藏
页码:1003 / 1005
页数:3
相关论文
共 73 条
[1]   The synthesis and structural analysis of the bis-Co2(CO)6 adduct of the cyclic tetrayne C20H8 [J].
Adams, RD ;
Bunz, UHF ;
Fu, W ;
Nguyen, L .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 578 (1-2) :91-94
[2]   Synthesis of mixed heterocalixarenes from benzofuranyl methanols and activated indoles [J].
Black, DS ;
Craig, DC ;
Rezaie, R .
CHEMICAL COMMUNICATIONS, 2002, (08) :810-811
[3]   NITRONES AND OXAZIRIDINES .45. FORMATION OF PYRROLO[1,2-A]INDOLES BY INTRAMOLECULAR NITRONE CYCLOADDITION [J].
BLACK, DS ;
CRAIG, DC ;
DEBDAS, RB ;
KUMAR, N .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1993, 46 (05) :603-622
[4]   CALIX[4]INDOLES - NEW MACROCYCLIC TETRA(INDOLYLMETHYLENE) COMPOUNDS WITH 2,7-LINKAGES [J].
BLACK, DS ;
CRAIG, DC ;
KUMAR, N .
TETRAHEDRON LETTERS, 1995, 36 (44) :8075-8078
[5]   Formation of C-amido-calix[3]indoles from 2′- and 7′-indolylglyoxylamides [J].
Black, DS ;
Kumar, N ;
McConnell, DB .
TETRAHEDRON, 2000, 56 (43) :8513-8524
[6]  
Black DS, 1996, HETEROATOM CHEM, V7, P437, DOI 10.1002/(SICI)1098-1071(199611)7:6<437::AID-HC6>3.0.CO
[7]  
2-5
[8]  
Bodwell GJ, 2002, ANGEW CHEM INT EDIT, V41, P4003, DOI 10.1002/1521-3773(20021104)41:21<4003::AID-ANIE4003>3.0.CO
[9]  
2-#
[10]  
Bodwell GJ, 2002, ANGEW CHEM INT EDIT, V41, P3261, DOI 10.1002/1521-3773(20020902)41:17<3261::AID-ANIE3261>3.0.CO