Synthesis and structure of electron-deficient trimethylacetatocobalt(II) 3,5-dimethylpyrazole complexes, which are structural analogs of the active site of metalloenzymes

被引：15

作者：

Denisova, T. O. ^{[1
]}

Dobrokhotova, Zh. B.

Ikorskii, V. N.

Nefedov, S. E.

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 31, Moscow 119991, Russia

[2] Russian Acad Sci, Siberian Div, Int Tomog Ctr, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 51卷 / 09期

基金：

俄罗斯基础研究基金会;

关键词：

Electron transitions - Enzyme kinetics - Mathematical models - Metal analysis - Synthesis (chemical);

D O I：

10.1134/S0036023606090051

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The formation laws of [Co-2(mu-OOCR)(2)L-4](2+) binuclear complexes, which model the active site of metalloenzymes, are studied.

引用

页码：1363 / 1403

页数：41

共 20 条

[1] Synthetic modeling of the active site of native metalloenzymes by trimethylacetatozinc complexes [J].

Amel'chenkova, E. V. ;

Denisova, T. O. ;

Nefedov, S. E. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 51 (08) :1218-1263

[2]

[Anonymous], 1979, ORGANIKUM, V2

[3]

[Anonymous], 1997, SMART CONTR SAINT IN

[4] Interaction of urea with a hydroxide-bridged dinuclear nickel center: An alternative model for the mechanism of urease [J].

Barrios, AM ;

Lippard, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (38) :9172-9177

[5]

Cotton F., 1999, ADV INORGANIC CHEM

[6] Copper(II) trimethylacetate complexes with 3,5-dimethylpyrazole [J].

Denisova, T. O. ;

Amel'chenkova, E. V. ;

Pruss, I. V. ;

Dobrokhotova, Zh. V. ;

Fialkovskii, O. P. ;

Nefedov, S. E. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 51 (07) :1020-1064

[7] Synthesis and structure of the binuclear and mononuclear complexes Co2(μ-OH2)2(μ-OOCBut)2(Hdmpz)4[OS(O)2CF3]2•2THF and Co(Hdmpz)2(MeCN)2(OH2)2[OS(O)2CF3]2•THF (Hdmpz=3,5-dimethylpyrazole) [J].

Denisova, TO ;

Nefedov, SE .

MENDELEEV COMMUNICATIONS, 2003, (04) :161-162

[8]

DENISOVA TO, 2003, IZV AKAD NAUK K, P982

[9]

DENISOVA TO, 2003, ZH NEORG KHIM, V49, P1476

[10]

DENISOVA TO, 2003, IZV AKAD NAUK K, P1552

← 1 2 →