Solvent-free microwave-assisted peroxidative oxidation of secondary alcohols to the corresponding ketones catalyzed by copper(II) 2,4-alkoxy-1,3,5-triazapentadienato complexes

被引：73

作者：

Figiel, Pawel J. ^{[1
]}

Kopylovich, Maximilian N. ^{[1
]}

Lasri, Jamal ^{[1
]}

Guedes da Silva, M. Fatima C. ^{[1
,2
]}

Frausto da Silva, Joao J. R. ^{[1
]}

Pombeiro, Armando J. L. ^{[1
]}

机构：

[1] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal

[2] ULHT Lisbon, P-1749024 Lisbon, Portugal

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 16期

关键词：

T-BUTYL HYDROPEROXIDE; HYDROGEN-PEROXIDE; EFFICIENT; LIGANDS; CO; TRINUCLEAR; CLEAVAGE; CRYSTAL; OLEFINS; ALKANES;

D O I：

10.1039/b922738e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile, efficient and selective solvent-free synthesis of ketones from secondary alcohols with tert-butylhydroperoxide (TBHP) as the oxidant under microwave irradiation is achieved, where the copper(II) 2,4-alkoxy-1,3,5-triazapentadienato complexes are efficient catalysts providing high yields (up to 100%), TONs (up to 890) and TOFs (up to 1780 h(-1)).

引用

页码：2766 / 2768

页数：3

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