A Clean, Mild, and Selective Oxidation of Sulfides to Sulfoxides Using NaClO/H2SO4 in Aqueous Media

被引：21

作者：

Amoozadeh, Ali ^{[1
]}

Nemati, Firouzeh ^{[1
]}

机构：

[1] Semnan Univ, Dept Chem, Fac Sci, Semnan, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2009年 / 184卷 / 10期

关键词：

Green chemistry; oxidation; sodium hypochlorite; sulfide; sulfoxide; EFFICIENT OXIDATION; HYDROGEN-PEROXIDE; ORGANIC-SYNTHESIS; THIOLS; HYPOCHLORITE; DISULFIDES; SULFONES; SULFUR; ACID;

D O I：

10.1080/10426500802529226

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

A range of sulfides can be selectively oxidized to the corresponding sulfoxides in good yields using NaClO/H2SO4 in both water and 50:50 water:EtOH as solvent. Two new compounds are reported that show a diastereoselective oxidation in 2-phenylthioalcohols with possible neighboring hydroxyl group participation with a logic proposed mechanism.

引用

收藏

页码：2569 / 2575

页数：7

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