Thermal Behavior of Methylammonium Lead-Trihalide Perovskite Photovoltaic Light Harvesters

被引:504
作者
Dualeh, Amalie [1 ]
Gao, Peng [1 ]
Seok, Sang Il [2 ,3 ]
Nazeeruddin, Mohammad Khaja [1 ]
Graetzel, Michael [1 ]
机构
[1] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Lab Photon & Interfaces, Stn 6, CH-1015 Lausanne, Switzerland
[2] Korea Res Inst Chem Technol, Div Adv Mat, Taejon 305600, South Korea
[3] Sungkyunkwan Univ, Dept Energy Sci, Suwon 440746, South Korea
基金
新加坡国家研究基金会;
关键词
HYBRID SOLAR-CELLS; EFFICIENT; TEMPERATURE; DEPOSITION; TRANSPORT;
D O I
10.1021/cm502468k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently organicinorganic hybrid perovskites have attracted attention as light harvesting materials in mesoscopic cells. While a considerable number of deposition and formation methods have been reported for the perovskite crystalline material, most involve an annealing step. As such, the thermal behavior of this material and its individual components is of crucial interest. Here, we examine the thermal properties of the CH3NH3PbX3 (X = I or Cl) perovskite using thermogravimetric analysis. The role of the precursors is exposed, and the effect of the formation of excess organic species is investigated. The sublimation behavior of the organic component is intensively scrutinized. Furthermore, differential scanning calorimetry is employed to probe the crystal phase structure, revealing subtle differences depending on the deposition method.
引用
收藏
页码:6160 / 6164
页数:5
相关论文
共 24 条
[1]   Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3) PbI3 for solid-state sensitised solar cell applications [J].
Baikie, Tom ;
Fang, Yanan ;
Kadro, Jeannette M. ;
Schreyer, Martin ;
Wei, Fengxia ;
Mhaisalkar, Subodh G. ;
Graetzel, Michael ;
White, Tim J. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5628-5641
[2]   Low-temperature processed meso-superstructured to thin-film perovskite solar cells [J].
Ball, James M. ;
Lee, Michael M. ;
Hey, Andrew ;
Snaith, Henry J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1739-1743
[3]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[4]   MAPbl3-x Clx Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties [J].
Colella, Silvia ;
Mosconi, Edoardo ;
Fedeli, Paolo ;
Listorti, Andrea ;
Gazza, Francesco ;
Orlandi, Fabio ;
Ferro, Patrizia ;
Besagni, Tullo ;
Rizzo, Aurora ;
Calestani, Gianluca ;
Gigli, Giuseppe ;
De Angelis, Filippo ;
Mosca, Roberto .
CHEMISTRY OF MATERIALS, 2013, 25 (22) :4613-4618
[5]   Effect of Annealing Temperature on Film Morphology of Organic-Inorganic Hybrid Pervoskite Solid-State Solar Cells [J].
Dualeh, Amalie ;
Tetreault, Nicolas ;
Moehl, Thomas ;
Gao, Peng ;
Nazeeruddin, Mohammad Khaja ;
Graetzel, Michael .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (21) :3250-3258
[6]   High Open-Circuit Voltage Solar Cells Based on Organic-Inorganic Lead Bromide Perovskite [J].
Edri, Eran ;
Kirmayer, Saar ;
Cahen, David ;
Hodes, Gary .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (06) :897-902
[7]   Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells [J].
Eperon, Giles E. ;
Stranks, Samuel D. ;
Menelaou, Christopher ;
Johnston, Michael B. ;
Herz, Laura M. ;
Snaith, Henry J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (03) :982-988
[8]   Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells [J].
Eperon, Giles E. ;
Burlakov, Victor M. ;
Docampo, Pablo ;
Goriely, Alain ;
Snaith, Henry J. .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (01) :151-157
[9]  
Erk P., 2014, CHEM CHALLENGES SOFT
[10]  
Fahlman BD, 2000, ADV MATER OPT ELECTR, V10, P223, DOI 10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO