Role of ITO and PEDOT:PSS in stability/degradation of polymer: fullerene bulk heterojunctions solar cells

被引:135
作者
Girtan, M. [1 ]
Rusu, M. [2 ]
机构
[1] Univ Angers, Lab POMA, FRE 2988, CNRS, F-49045 Angers, France
[2] Alexandru Ioan Cuza Univ, Iasi 700506, Romania
关键词
PCBM; P3HT; MDMO-PPV; Organic solar cells; ORGANIC PHOTOVOLTAICS; DEGRADATION; LIFETIMES; VACUUM; FILMS; OXIDE; AIR;
D O I
10.1016/j.solmat.2009.10.026
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Two polymers: fullerene bulk heterojunction solar cells: [(1) poly[ 2-methoxy-5-(3,7-dimethyloctyloxy)]-1,4-phenylenevinylene (MDMO-PPV): methanofullerene phenyl-C-61-butyric-acid-methyl-ester ([60]PCBM) and (11) poly(3-hexylthiophene-2,5-diyl), highly regioregular (P3HT): [60]PCBM] were studied. Indium tin oxide (ITO) and/or poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) were/was used as transparent electrode, and lithium fluoride (LiF) was used as buffer layer for aluminium cathode. The role of ITO and PEDOT:PSS on the current-tension characteristics, on open circuit voltage V-OC and on density of short-circuit current J(SC) was investigated for the two polymers:PCBM blend solar cells as deposited and after 40 days ageing. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:446 / 450
页数:5
相关论文
共 34 条
[1]  
ALIBRAHIM M, 2005, APPL PHYS LETT, V83, P1
[2]   Characterization of organic solar cells: the importance of device layout [J].
Cravino, Antonio ;
Schilinsky, Pavel ;
Brabec, Christoph J. .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (18) :3906-3910
[3]   Indium diffusion in model polymer light-emitting diodes [J].
de Jong, MP ;
Simons, DPL ;
Reijme, MA ;
van IJzendoorn, LJ ;
van der Gon, AWD ;
de Voigt, MJA ;
Brongersma, HH ;
Gymer, RW .
SYNTHETIC METALS, 2000, 110 (01) :1-6
[4]   Bulk heterojunctions based on native polythiophene [J].
Gevorgyan, Suren A. ;
Krebs, Frederik C. .
CHEMISTRY OF MATERIALS, 2008, 20 (13) :4386-4390
[5]   Characterization of the PEDOT-PSS system by means of X-ray and ultraviolet photoelectron spectroscopy [J].
Greczynski, G ;
Kugler, T ;
Salaneck, WR .
THIN SOLID FILMS, 1999, 354 (1-2) :129-135
[6]   Stability/degradation of polymer solar cells [J].
Jorgensen, Mikkel ;
Norrman, Kion ;
Krebs, Frederik C. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (07) :686-714
[7]   Efficient tandem polymer solar cells fabricated by all-solution processing [J].
Kim, Jin Young ;
Lee, Kwanghee ;
Coates, Nelson E. ;
Moses, Daniel ;
Nguyen, Thuc-Quyen ;
Dante, Mark ;
Heeger, Alan J. .
SCIENCE, 2007, 317 (5835) :222-225
[8]   New architecture for high-efficiency polymer photovoltaic cells using solution-based titanium oxide as an optical spacer [J].
Kim, JY ;
Kim, SH ;
Lee, HH ;
Lee, K ;
Ma, WL ;
Gong, X ;
Heeger, AJ .
ADVANCED MATERIALS, 2006, 18 (05) :572-+
[9]   A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene: fullerene solar cells [J].
Kim, Y ;
Cook, S ;
Tuladhar, SM ;
Choulis, SA ;
Nelson, J ;
Durrant, JR ;
Bradley, DDC ;
Giles, M ;
Mcculloch, I ;
Ha, CS ;
Ree, M .
NATURE MATERIALS, 2006, 5 (03) :197-203
[10]  
Kireev P., 1978, SEMICONDUCTOR PHYS