New reactions in water:: metal-free conversion of alcohols and ketones into α-iodoketones

被引：53

作者：

Barluenga, J ^{[1
]}

Marco-Arias, M ^{[1
]}

González-Bobes, F ^{[1
]}

Ballesteros, A ^{[1
]}

González, JM ^{[1
]}

机构：

[1] Univ Oviedo, Inst Quim Organomet Enrique Moles, E-33006 Oviedo, Spain

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 22期

关键词：

D O I：

10.1039/b411227j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using water as the reaction medium, ketones can be transformed into alpha-iodoketones upon treatment with sodium iodide, hydrogen peroxide and an acid; interestingly, alpha-iodoketones can be also obtained from secondary alcohols through a metal-free tandem oxidation - iodination approach.

引用

页码：2616 / 2617

页数：2

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