Picosecond hydrogen transfer in the phenol-(NH3)n=1-3 excited state

被引：65

作者：

Grégoire, G ^{[1
]}

Dedonder-Lardeux, C ^{[1
]}

Jouvet, C ^{[1
]}

Martrenchard, S ^{[1
]}

Peremans, A ^{[1
]}

Solgadi, D ^{[1
]}

机构：

[1] Univ Paris 11, CNRS, Photophys Mol Lab, F-91405 Orsay, France

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2000年 / 104卷 / 40期

关键词：

D O I：

10.1021/jp001475f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The phenol-(NH3)(n=1,2,3) (S-1) lifetimes have been measured near their band origins by a picosecond pump/probe scheme. The very short lifetimes observed reveal that the excited clusters undergo a reactive process, namely the following dissociative hydrogen transfer reaction: PhOH*-(NH3)(n) --> PhO. + NH4(NH3)(n-1).

引用

页码：9087 / 9090

页数：4

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