[Co(Co)5][(CF3)3BF]:: A stable salt of a homoleptic trigonal-bipyramidal metal-carbonyl cation

被引：29

作者：

Bernhardt, E

Finze, M

Willner, H

Lehmann, CW

Aubke, F

机构：

[1] Univ Duisburg Gesamthsch, Fak Anorgan Chem 4, D-47048 Duisburg, Germany

[2] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

[3] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 18期

关键词：

borates; carbonyl ligands; cobalt complexes; structure elucidation; superacids;

D O I：

10.1002/anie.200250780

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cobalt takes to superacid: By using the superacid system (CF3)3BCO and anhydrous HF the title complex (see structure O blue, C black, Co cyan, F red, B light brown) is formed in a one pot reaction of [CO2(CO)8]. The oxidizing agent is postulated to be H2Fsolv.+ which is generated in situ.

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页码：2077 / 2079

页数：3

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