Unique chains of alternating octahedral and tetrahedral cobalt(II) sites:: crystal structures of the novel chloro-bridged complexes [Co4(μ-Cl)6Cl2(thf)4(MeOH)2]n and [{Co4(μ-Cl)6Cl2(thf)4(H2O)2}•2THF]n

被引：18

作者：

Hierso, JC

Ellis, DD

Spek, AL

Bouwman, E

Reedijk, J

机构：

[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 15期

关键词：

D O I：

10.1039/b003213l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Co-4(mu-Cl)(6)Cl-2(thf)(4)(MeOH)(2)](n), a catena-polycobalt(ii) complex with an unusual linear chain of octahedral/tetrahedral/octahedral cobalt sites, is obtained quantitatively from the reaction between cobalt chloride hydrate and trimethylorthoformate in THF.

引用

页码：1359 / 1360

页数：2

共 22 条

[1]

ALRESAYES PB, 1991, J CHEM SOC CHEM COMM, P78

[2] SYNTHESIS AND SPECTROSCOPY OF COORDINATION-COMPOUNDS OF A VERSATILE BRIDGING LIGAND - MOLECULAR-STRUCTURES OF THE DINUCLEAR COMPOUNDS [CO-2(BDNOL)(NCS)(3)], [ZN-2(BDNOL)CL(NCS)(2)], AND [CU(BDNOL)(NO3)(3)] AND OF THE POLYMERIC COPPER(I) COMPOUND [CU-2(HBDNOL)(NCS)(2)] [J].