Structural and catalytic properties of bis(guanidine)copper(I) halides

被引：59

作者：

Oakley, SH ^{[1
]}

Coles, MP ^{[1
]}

Hitchcock, PB ^{[1
]}

机构：

[1] Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 10期

关键词：

D O I：

10.1021/ic034213b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The neutral, bicyclic guanidine 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) coordinates to Cu(l) halides via the imine nitrogen, and the complexes are stabilized by intramolecular (NHX)-X-... interactions (X = Cl, Br) or are partially dissociated (X = l) in the solid state; in all cases, fluxional behavior is observed in solution. Selected complexes have been tested as catalysts for the polymerization of methyl methacrylate.

引用

页码：3154 / 3156

页数：3

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