Reactivity of organometallic molybdate toward lanthanide cations. Synthesis and structure of polynuclear lanthanide-molybdate complexes

被引：16

作者：

Hashimoto, M ^{[1
]}

Takata, M

Yagasaki, A

机构：

[1] Wakayama Univ, Fac Syst Engn, Dept Mat Sci & Chem, Wakayama 6408510, Japan

[2] Kwansei Gakuin Univ, Sch Sci, Dept Chem, Nishinomiya, Hyogo 6628501, Japan

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 16期

关键词：

D O I：

10.1021/ic991221c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel polynuclear rare earth compounds [La-3(OH2)(7)-(Cp*MoO3)(2)(NO3)(7)] and [La-3(OH2)(5)(THF)(Cp*MoO3)(2)-(NO3)(6)](2)(NO3)(2) were synthesized by reacting [(n-C4H9)(4)N][CP*MoO3] With La(NO3)(3). 6H(2)O in THF. X-ray crystal structural analyses revealed that both these compounds are composed of a La3Mo2O6 unit in which the metal atoms arrange themselves into a trigonal bipyramid. The Ce analogues were also obtained. [GRAPHICS]

引用

页码：3712 / +

页数：4

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[No title captured]

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