Isolation and characterization of a monomeric, solvent coordinated ruthenium(II)carbene cation relevant to olefin metathesis

被引：27

作者：

Hofmann, P ^{[1
]}

Volland, MAO ^{[1
]}

Hansen, SM ^{[1
]}

Eisenträger, F ^{[1
]}

Gross, JH ^{[1
]}

Stengel, K ^{[1
]}

机构：

[1] Ruprecht Karl Univ Heidelberg, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 606卷 / 01期

关键词：

ruthenium; carbene complexes; metathesis; homogenous catalysis; density functional theory calculations;

D O I：

10.1016/S0022-328X(00)00288-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The isolation as well as spectroscopic and structural characterization of [(kappa(2)-'Bu2PCPH2P'Bu-2)ClRu-CH-CH=C(CH3)(2)-(CH3CN)](+) ([5(+)]), a solvent-coordinated monomeric ruthenium(II)carbene cation with a rigid cis-stereochemistry of two phosphines, are reported. Its relevance for the mechanism of olefin metathesis catalyzed by such complexes is discussed and distinct differences compared to complexes with the usual trans-phosphine stereochemistry are noted. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：88 / 92

页数：5

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