Ruthenium-catalysed cleavage of alkenes and alkynes to carboxylic acids

被引:41
作者
Griffith, WP [1 ]
Shoair, AG [1 ]
Suriaatmaja, M [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
关键词
D O I
10.1080/00397910008086915
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Catalysis of alkene and alkyne cleavage to carboxylic acids by ruthenium trichloride in the presence of an excess of periodic acid has been studied in biphasic H2O - CC4-CH3CN media, and is found to be simple and effective. The active catalyst is shown to be RuO4.
引用
收藏
页码:3091 / 3095
页数:5
相关论文
共 12 条
[1]   Studies on transition metal nitrido and oxo complexes .16(1). The nature of the oxoruthenates involved in some ruthenium-catalysed organic oxidations [J].
Bailey, AJ ;
Cother, LD ;
Griffith, WP ;
Hankin, DM .
TRANSITION METAL CHEMISTRY, 1995, 20 (06) :590-594
[2]   A GREATLY IMPROVED PROCEDURE FOR RUTHENIUM TETRAOXIDE CATALYZED OXIDATIONS OF ORGANIC-COMPOUNDS [J].
CARLSEN, PHJ ;
KATSUKI, T ;
MARTIN, VS ;
SHARPLESS, KB .
JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (19) :3936-3938
[3]  
CHANG JM, 1983, J ORG CHEM, V50, P1560
[4]   CHEMISTRY OF RU(VI), RU(VII) AND RU(VIII) - REACTIONS, OXIDATION POTENTIALS AND SPECTRA [J].
CONNICK, RE ;
HURLEY, CR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (20) :5012-5015
[5]   TRANSITION-METAL PERIODATO COMPLEXES - THEIR PREPARATIONS AND PROPERTIES AS CATALYTIC OXIDANTS, AND X-RAY CRYSTAL-STRUCTURE OF NA4K[AU(IO5(OH))2].KOH.15H2O [J].
DENGEL, AC ;
ELHENDAWY, AM ;
GRIFFITH, WP ;
MOSTAFA, SI ;
WILLIAMS, DJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (24) :3489-3495
[6]  
GOPAL H, 1971, TETRAHEDRON LETT, P2941
[7]   RAMAN SPECTRA OF RUTHENIUM TETROXIDE AND RELATED SPECIES [J].
GRIFFITH, WP .
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (07) :1663-&
[8]   Ruthenate(VI)-catalysed dehydrogenation of primary amines to nitriles, and crystal structures of cis-[Ru(bipy)2(NH2CH2Ph)2][PF6]2•0.5MeOH and cis-[Ru(bipy)2(NCPh)2][PF6]2•CH2Cl2 [J].
Griffith, WP ;
Reddy, B ;
Shoair, AGF ;
Suriaatmaja, M ;
White, AJP ;
Williams, DJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (17) :2819-2825
[9]   RU-CATALYZED OXIDATION OF ACETYLENES TO ALPHA-DIKETONES WITH IODOSYLBENZENE [J].
MULLER, P ;
GODOY, J .
HELVETICA CHIMICA ACTA, 1981, 64 (08) :2531-2533
[10]   EFFICIENT OXIDATION OF PHENYL GROUPS TO CARBOXYLIC-ACIDS WITH RUTHENIUM TETRAOXIDE - A SIMPLE SYNTHESIS OF (R)-GAMMA-CAPROLACTONE, THE PHEROMONE OF TROGODERMA-GRANARIUM [J].
NUNEZ, MT ;
MARTIN, VS .
JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (06) :1928-1932