Formation of manganese enediyne complexes from manganese alkynylcarbene complexes

被引：12

作者：

Casey, CP ^{[1
]}

Dzwiniel, TL ^{[1
]}

Kraft, S ^{[1
]}

Kozee, MA ^{[1
]}

Powell, DR ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

INORGANICA CHIMICA ACTA | 2003年 / 345卷

关键词：

manganese alkynylcarbene complexes; enediyne; manganese alkyne complexes;

D O I：

10.1016/S0020-1693(02)01273-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dimerization of the alkynylcarbene complex (C5H4Me)(CO)(2)Mn=C(Tol)C=CTol (10) occurred at 65 degreesC to give a mixture of E- and Z-enediyne complexes [(C5H4Me)(OC)(2)Mn](2)[eta(2), eta(2)-TolC=C(Tol)C=C(Tol)C=CTol] (13). Thermolysis of alkynye complexes 10 at higher (100 degreesC) temperature led to the formation of manganese-free E- and Z-enediynes TolC=C(Tol)C=C(Tol)C=CTol (14-E and 14-Z). Attempted synthesis of the tethered bis-(alkynylcarbene) Complex Cp(OC)(2)Mn=C(Ph)C=CCH2CH2CH2C=CC(Ph)= Mn(CO)(2)CP led instead to the cyclic enediyne complex [Cp(OC)(2)Mn](2)[eta(2), eta(2)-PhC=CC(CH2CH2CH2)=CC=CPh] (19), from which the metal-free enediyne 1,2-bis(phenylethynyl)cyclopentene (20) was released by thermolysis at 90 degreesC. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：320 / 326

页数：7

共 35 条

[1] (1-alkynyl)carbene complexes (equals 1-metalla-1-buten-3-ynes): Tools for synthesis
Aumann, R
Nienaber, H
[J]. ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 41, 1997, 41 : 163 - 242
[2] SYNTHESIS AND CRYSTAL-STRUCTURE OF DIPHENYLCARBENE(PENTACARBONYL)TUNGSTEN(0)
CASEY, CP
BURKHARDT, TJ
BUNNELL, CA
CALABRESE, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (07) : 2127 - 2134
[3] Formation of cis-enediyne complexes from rhenium alkynylcarbene complexes
Casey, CP
Kraft, S
Powell, DR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (11) : 2584 - 2594
[4] Reaction of rhenium alkynyl carbene complexes with tertiary phosphines produces dihydrophospholium rhenium complexes by a formal CH insertion process
Casey, CP
Kraft, S
Powell, DR
Kavana, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 617 (01) : 723 - 736
[5] Intramolecular CH insertion reactions of (pentamethylcyclopentadienyl)Rhenium alkynylcarbene complexes
Casey, CP
Kraft, S
Kavana, M
[J]. ORGANOMETALLICS, 2001, 20 (17) : 3795 - 3799
[6] THERMOLYSIS OF (2-OXACYCLOPENTYLIDENE)PENTACARBONYLCHROMIUM(0) - EVIDENCE AGAINST FREE CARBENES IN THERMAL-DECOMPOSITION OF METAL-CARBENE COMPLEXES
CASEY, CP
ANDERSON, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (21) : 895 - 896
[7] Dimerization of rhenium alkynyl carbene complexes by a process involving two [1,1.5] rhenium shifts and coupling of the remote alkynyl carbons
Casey, CP
Kraft, S
Powell, DR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (15) : 3771 - 3772
[8] INSITU GENERATION AND REACTIONS OF (CO)5WC(C6H5)H WITH ALKENES - ROLE OF PUCKERED METALLOCYCLOBUTANES IN DETERMINING STEREOCHEMISTRY OF CYCLOPROPANE FORMATION
CASEY, CP
POLICHNOWSKI, SW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (18) : 6097 - 6099
[9] de Meijere A, 2000, ANGEW CHEM INT EDIT, V39, P3964, DOI 10.1002/1521-3773(20001117)39:22<3964::AID-ANIE3964>3.0.CO
[10] 2-C

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