Crystal design of organic conductors using the iodine bond

被引：7

作者：

Imakubo, T ^{[1
]}

Tajima, N

Shirahata, T

Miyake, A

Sawa, H

Nakamura, T

Ohnuki, H

Tamura, M

Kato, R

Izumi, M

Nishio, Y

Kajita, K

机构：

[1] RIKEN, Wako, Saitama 3510198, Japan

[2] Chiba Univ, Inage Ku, Chiba 2638522, Japan

[3] KEK, Tsukuba, Ibaraki 3050801, Japan

[4] IMS, Okazaki, Aichi 4448585, Japan

[5] Tokyo Univ Mercantile Marine, Koto Ku, Tokyo 1358533, Japan

[6] Toho Univ, Funabashi, Chiba 2748510, Japan

来源：

SYNTHETIC METALS | 2003年 / 135卷 / 1-3期

关键词：

organic superconductors; metal-insulator phase transition; conductivity; electrocrystallization; X-ray diffraction;

D O I：

10.1016/S0379-6779(02)00786-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The iodine-based intermolecular interaction, i.e. iodine bond is highly useful for structure control of organic conductors and a wide variety of supramolecular conductors including a superconductor have been developed. In this paper, we focus our attention on exotic iodinated donor molecules DIETS (diiodo(ethylenedithio)diselenadithiafulvalene) and DIETSe (diiodo(ethylenedithio)tetraselenafulvalene). Syntheses, structure and electronic properties of a supramolecular superconductor and a new series of organic metals are reported together with an outline of the iodine bonding architecture.

引用

页码：601 / 602

页数：2

共 9 条

[1] A SCALE OF ELECTRONEGATIVITY BASED ON ELECTROSTATIC FORCE [J].