Carbon-carbon bond formation by cyclization of dienes using phosphorus-centered radicals in water

被引：15

作者：

Cho, DY

Jang, DO ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Wonju 220710, South Korea

[2] Yonsei Univ, Ctr Bioact Mol Hybrids, Seoul 120749, South Korea

来源：

SYNLETT | 2005年 / 01期

关键词：

radical; cyclization; water; diene; phosphorus hydride;

D O I：

10.1055/s-2004-836041

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and mild methodology for preparing carbocyclic and heterocyclic compounds with phosphorus functionality by radical cyclization of dienes in water without using organic co-solvents has been developed. The reaction affords environmentally benign reaction conditions.

引用

页码：59 / 62

页数：4

共 39 条

[1]

Baguley PA, 1998, ANGEW CHEM INT EDIT, V37, P3073, DOI 10.1002/(SICI)1521-3773(19981204)37:22<3072::AID-ANIE3072>3.0.CO

[2]

2-9

[3] HYPOPHOSPHOROUS ACID AND ITS SALTS - NEW REAGENTS FOR RADICAL CHAIN DEOXYGENATION, DEHALOGENATION AND DEAMINATION [J].