Oxidative Heck-type reaction involving cleavage of a carbon-phosphorus bond of arylphosphonic acids

被引：108

作者：

Inoue, A ^{[1
]}

Shinokubo, H ^{[1
]}

Oshima, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 06期

关键词：

D O I：

10.1021/ja026758v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cleavage of a carbon-phosphorus bond is achieved under palladium catalysis in an oxidative Heck-type reaction which exploits arylphosphonic acids. The reaction of arylphosphonic acids with alkenes provides arylation products in good yields in the presence of TBAF with trimethylamine oxide as an oxidant. Copyright © 2003 American Chemical Society.

引用

页码：1484 / 1485

页数：2

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