Sandwiched Graphene-Membrane Superstructures

被引:241
作者
Titov, Alexey V. [1 ]
Kral, Petr [1 ]
Pearson, Ryan [1 ]
机构
[1] Univ Illinois, Dept Chem, Chicago, IL 60607 USA
关键词
graphene; lipid membrane; self-assembly; graphene composite; bioelectronics; WALLED CARBON NANOTUBES; COARSE-GRAINED MODEL; MOLECULAR-DYNAMICS; LIPID-BILAYERS; SIMULATIONS; PHOSPHOLIPIDS; DERIVATIVES; CURVATURE;
D O I
10.1021/nn9015778
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We demonstrate by molecular dynamics simulations that graphene sheets could be hosted in the hydrophobic interior of biological membranes formed by amphiphilic phospholipid molecules. Our simulation shows that these hybrid graphene-membrane superstructures might be prepared by forming hydrated micelles of individual graphene flakes covered by phospholipids, which can be then fused with the membrane. Since the phospholipid layers of the membrane electrically isolate the embedded graphene from the external solution, the composite system might be used in the development of biosensors and bioelectronic materials.
引用
收藏
页码:229 / 234
页数:6
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