Microcrystalline silicon germanium: An attractive bottom-cell material for thin-film silicon-based tandem-solar-cells
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作者:
Ganguly, G
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Electrotech Lab, Thin Film Silicon Solar Cells Superlab, Tsukuba, Ibaraki 305, JapanElectrotech Lab, Thin Film Silicon Solar Cells Superlab, Tsukuba, Ibaraki 305, Japan
Ganguly, G
[1
]
Ikeda, T
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Electrotech Lab, Thin Film Silicon Solar Cells Superlab, Tsukuba, Ibaraki 305, JapanElectrotech Lab, Thin Film Silicon Solar Cells Superlab, Tsukuba, Ibaraki 305, Japan
Ikeda, T
[1
]
Kajiwara, K
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Electrotech Lab, Thin Film Silicon Solar Cells Superlab, Tsukuba, Ibaraki 305, JapanElectrotech Lab, Thin Film Silicon Solar Cells Superlab, Tsukuba, Ibaraki 305, Japan
Kajiwara, K
[1
]
Matsuda, A
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Electrotech Lab, Thin Film Silicon Solar Cells Superlab, Tsukuba, Ibaraki 305, JapanElectrotech Lab, Thin Film Silicon Solar Cells Superlab, Tsukuba, Ibaraki 305, Japan
Matsuda, A
[1
]
机构:
[1] Electrotech Lab, Thin Film Silicon Solar Cells Superlab, Tsukuba, Ibaraki 305, Japan
We have prepared hydrogenated microcrystalline silicon germanium by plasma enhanced CVD of a mixture of silane and germane gas diluted with hydrogen. The growth conditions have been systematically controlled to obtain large (similar to 400 Angstrom) crystallites of silicon-germanium as observed using Raman scattering and x-ray diffraction. The dangling bond (germanium) density has been reduced to <5x10(16) cm(-3) at low substrate temperatures (similar to 150 degrees C). The optical absorption spectra of the 50% Ge containing material is red-shifted compared to microcrystalline silicon, consistent with a reduction of the indirect optical gap to 0.9eV. Schottky type cells fabricated using Au on an n(+) crystalline silicon substrate confirm that the long wavelength response is remarkably enhanced in this material.