Reversible n-doping of poly(nonylbithiazole) and oligomeric model compounds. Application as a Li battery electrode

被引:31
作者
Curtis, MD [1 ]
Cheng, HT
Nanos, JI
Nazri, GA
机构
[1] Univ Michigan, Dept Chem, Willard H Dow Labs, Ann Arbor, MI 48109 USA
[2] Univ Michigan, Macromol Sci & Engn Ctr, Ann Arbor, MI 48109 USA
[3] GM Corp, Ctr Res & Dev, Phys & Phys Chem Dept, Warren, MI 48090 USA
关键词
D O I
10.1021/ma971285b
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The electrochemical, optical, and conductivity properties of electrochemically n-doped films of poly(nonylbithiazole) and performance of the polymer as a lithium battery electrode are presented. Bithiazole-based polymers are capable of reversible n-doping, with a maximum doping level of about one electron per bithiazole unit. The doped polymer is transparent in the visible region of the spectrum and exhibits metallic-like absorption in the near infrared.
引用
收藏
页码:205 / 207
页数:3
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