The structure and dipole moment of the argon•fluorobenzene dimer

被引：21

作者：

Appleman, RA ^{[1
]}

Peebles, SA ^{[1
]}

Kuczkowski, RL ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1998年 / 446卷 / 1-2期

关键词：

fluorobenzene; argon; complex; microwave; spectrum;

D O I：

10.1016/S0022-2860(97)00380-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The 1:1 complex between fluorobenzene and argon has been investigated by Fourier transform microwave spectroscopy. Rotational transitions of the C6D5F monomer and C6D5F . Ar dimer were assigned. The deuterated dimer rotational constants resolve an ambiguity in the position of the Ar in the dimer, placing it more nearly over the fluorobenzene ring The dipole moments of the monomers and dimers were determined from rotational Stark effects and interpreted in terms of the induced moment in the argon. (C) 1998 Elsevier Science B.V.

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页码：55 / 61

页数：7

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