Zwitterionic Ladder Bis(arylethenyl)benzenes with Large Two-Photon Absorption Cross Sections

被引：39

作者：

Fukazawa, Aiko ^{[1
]}

Yamada, Hiroshi ^{[1
]}

Sasaki, Yutaka ^{[2
]}

Akiyama, Seiji ^{[2
]}

Yamaguchi, Shigehiro ^{[1
]}

机构：

[1] Nagoya Univ, Dept Chem, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Sci & Technol Res Ctr Inc, Mitsubishi Chem Grp, Aoba Ku, Yokohama, Kanagawa 2778502, Japan

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2010年 / 5卷 / 03期

基金：

日本学术振兴会;

关键词：

boron; phosphorus; pi interactions; two-photon absorption; zwitterions; NONLINEAR-OPTICAL-PROPERTIES; A-PI-A; MOLECULAR-STRUCTURES; TRIVALENT BORON; SINGLE-PHOTON; ORGANOBORON COMPOUNDS; CRYSTAL-STRUCTURES; ORGANIC-MOLECULES; ACCEPTOR; DONOR;

D O I：

10.1002/asia.200900517

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various phosphonium- and borate-bridged bis(arylethenyl)benzenes were synthesized. The large two-photon absorption (TPA) cross sections in these zwitterionic ladder π-electron systems revealed that the introduction of zwitterionic bridges in the coplanar π-conjugated framework is a powerful strategy for designing excellent TPA materials. 2010 Wiley-VCH Verlag GmbH&Co. KGaA.

引用

页码：466 / 469

页数：4

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