New approaches to the synthesis of unsymmetrical diaryl selenides

被引:83
作者
Beletskaya, IP
Sigeev, AS
Peregudov, AS
Petrovskii, PV
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia
关键词
diaryl selenide; aryl iodide; aryl triflate; aryldiazonium salts; trialkyltin arylselenide;
D O I
10.1016/S0022-328X(00)00265-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Unsymmetrical diaryl selenides PhSeAr were obtained by the palladium catalysed reactions of aryl (heteroaryl) iodide or triflate with Bu3SnSePh in high yields. The same compounds can be obtained by the non-catalytic reactions of Bu3SnSePh with ArN2BF4 or (ArN2)(2)ZnCl4. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:96 / 101
页数:6
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