Polystyrene/montmorillonite nanocomposites prepared by in situ intercalative polymerization: Influence of the surfactant type

Na-montmorillonite (MM'T) with a cation ex change capacity (CEC) of 90 meq/100 g,was converted to MMT-CTAB and MMT-CPC by the intercalation of cetyltrimethylammonium bromide (CTAB) and cetylpyridinium: chloride (CPC), respectively. The intercalation of CPC onto the basal space of the montmorillonite expanded the basal space from 12.19 to 21.47 Angstrom, whereas in the case of CTAB, the spacing was only expanded to 19.35 Angstrom. The MMT-CPC and MMT-CTAB forms were subsequently used as hosts for the preparation of polystyrene nanocomposites via intercalative free-radical polymerization of styrene. Different structures were obtained by varying the preparation conditions; the exfoliated and intercalated nanocomposites were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA), and differentia scanning calorimeter (DSC). The produced nanocomposite exhibited improved thermal stability in comparison with that of pure polystyrene above 400 degreesC especially in the case of the nanocomposites based on the MMT=CPC, in which intercalation exists. A glass-transition temperature (Tg) could not be detected for the prepared nanocomposites using DSC this was assumed to result from the restricted molecular motion of the polymer chains.