The first iodine induced halide abstraction reaction:: synthesis and molecular structure of fac-[Re(CO)3(NCMe)3]•BrI2

被引：9

作者：

Baker, PK ^{[1
]}

Drew, MGB

Meehan, MM

机构：

[1] Univ Wales, Dept Chem, Bangor LL57 2UW, Gwynedd, Wales

[2] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 07期

关键词：

iodine-induced halide abstraction; fac-[Re(CO)(3)(NCMe)(3)]center dot BrI2; crystal structure;

D O I：

10.1016/S1387-7003(00)00093-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Equimolar quantities of [ReBr(CO)(5)] and I-2 react in refluxing acetonitrile for 5 h to give the cationic tris(acetonitrile) complex fac-[Re(CO)(3)(NCMe)(3)] . BrI2 (1) in a quantitative yield, via the first iodine promoted halide abstraction reaction. The structure of 1 has, as expected, a facial arrangement of carbonyl and acetonitrile ligands, with the linear anion, BrI2 as the counter ion. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：393 / 396

页数：4

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