Triphosphamacrocycle complexes of rhodium(III), iron(II) and ruthenium(II); crystal structure of trichloro[1,5,9-tris(2-propyl)-1,5,9-triphosphacyclododecane]rhodium(III)

被引：11

作者：

Edwards, PG

Fleming, JS

Coles, SJ

Hursthouse, MB

机构：

[1] Department of Chemistry, University of Wales Cardiff, Cardiff, CF1 3TB

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a703339g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The free macrocyclic 1,5,9-tris(2-propyl)-1,5,9-triphosphacyclododecane (Pr-3(i)[12]aneP(3), L) has been used for the first time to prepare a range of metal complexes. Reaction of L with RhCl3 . 3H(2)O yields the six-co-ordinate fac-octahedral complex [RhCl3(L)], which has been structurally characterises and is also used to prepare the analogous rhodium(III)-trihydrido and -triiodo complexes. The half-sandwich complex, [Fe(eta(5)-C5H5)(Lj)]PF6 was prepared from [Fe(eta(5)-G(5)H(5))(eta(6)-C6H5)]PF6 and L. The ruthenium complexes [RuCl2(dmso)(L)] (dmso = dimethyl sulfoxide) and [Ru-2(mu-Cl)(3)(L)(2)]Cl were also formed from the reaction of L with [RuCl2(dmso)(4)] and [RuCl2-(eta(6)-C6H4Me-4-Pr-i-1)](2) respectively.

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页码：3201 / 3206

页数：6

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