Quantum mechanical study of the F+D2→DF+D reaction

被引：37

作者：

Honvault, P ^{[1
]}

Launay, JM ^{[1
]}

机构：

[1] Univ Rennes 1, PALMS, CNRS, UMR 6627, F-35042 Rennes, France

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 287卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(98)00181-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A quantum-mechanical calculation of differential and integral cross sections for the F + D-2(nu = 0,j = 0,1,2) --> DF(nu'j') + D reaction has been performed using the ab initio potential energy surface of Stark and Werner. The hyperspherical method has been used and results have been obtained at two collision energies (90 and 140 meV). Bimodal rotational distributions for backward scattering and a forward scattering for nu' = 4 have been Found, in semi-quantitative agreement with recent crossed beam experiments. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：270 / 274

页数：5

共 32 条

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