Solid state lithium ion conduction in pyrrolidinium imide-lithium imide salt mixtures

被引：44

作者：

Huang, JH

Forsyth, M

MacFarlane, DR ^{[1
]}

机构：

[1] Monash Univ, Dept Chem, Clayton, Vic 3168, Australia

[2] Monash Univ, Dept Mat Engn, Clayton, Vic 3168, Australia

来源：

SOLID STATE IONICS | 2000年 / 136卷

关键词：

pyrrolidinium bis(trifluoromethane sulfonyl) imide; lithium bis(trifluoromethane sulfonyl) imide; plastic crystal; ionic conductor;

D O I：

10.1016/S0167-2738(00)00450-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The properties of the binary salt system based on mixtures of methyl ethyl pyrrolidinium bis(trifluoromethane sulfonyl) imide (P-12) and lithium bis(trifluoromethane sulfonyl) imide (Li imide) are repor ted. The lithium containing mixtures were found to be more than two orders of magnitude more conductive than the parent P-12 phase and the 33 mol% Li imide systems showed a solid state conductivity around 1 X 10(-4) S/cm at 20 degreesC. This solid state conductivity is believed to take place in plastic crystal phases of the P-12 compound. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：447 / 452

页数：6

共 10 条

[1] AMBIENT-TEMPERATURE PLASTIC CRYSTAL FAST ION CONDUCTORS (PLICFICS)
COOPER, EI
ANGELL, CA
[J]. SOLID STATE IONICS, 1986, 18-9 : 570 - 576
[2] FORSYTH M, UNPUB J MAT CHEM
[3] STUDIES OF THE ANISOTROPIC SELF-DIFFUSION AND REORIENTATION OF BUTYLAMMONIUM CATIONS IN THE ROTATOR PHASE OF BUTYLAMMONIUM CHLORIDE USING H-1 MAGNETIC-RESONANCE, ELECTRICAL-CONDUCTIVITY AND THERMAL MEASUREMENTS
HATTORI, M
FUKADA, SI
NAKAMURA, D
IKEDA, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (22): : 3777 - 3783
[4] Phase transitions and ionic motions in solid trimethylethylammonium iodide studied by H-1 and I-127 NMR, electrical conductivity, X-ray diffraction, and thermal analysis
Ishida, H
Furukawa, Y
Kashino, S
Sato, S
Ikeda, R
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1996, 100 (04): : 433 - 439
[5] IONIC DYNAMICS IN THE ROTATOR PHASE OF N-ALKYLAMMONIUM CHLORIDES (C-6-C-10), STUDIED BY H-1 NUCLEAR-MAGNETIC-RESONANCE, ELECTRICAL-CONDUCTIVITY AND THERMAL MEASUREMENTS
IWAI, S
HATTORI, M
NAKAMURA, D
IKEDA, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (05): : 827 - 831
[6] Pyrrolidinium imides: A new family of molten salts and conductive plastic crystal phases
MacFarlane, DR
Meakin, P
Sun, J
Amini, N
Forsyth, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (20) : 4164 - 4170
[7] Lithium-doped plastic crystal electrolytes exhibiting fast ion conduction for secondary batteries
MacFarlane, DR
Huang, JH
Forsyth, M
[J]. NATURE, 1999, 402 (6763) : 792 - 794
[8] New rotator phase revealed in di-n-alkylammonium bromides studied by solid-state NMR, powder XRD, electrical conductivity and thermal measurements
Shimizu, T
Tanaka, S
OnodaYamamuro, N
Ishimaru, S
Ikeda, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (02): : 321 - 326
[9] NOVEL IONIC PLASTIC PHASE OF ((CH3)4N)SCN OBTAINABLE ABOVE 455-K STUDIED BY PROTON MAGNETIC-RESONANCE, ELECTRICAL-CONDUCTIVITY AND THERMAL MEASUREMENTS
TANABE, T
NAKAMURA, D
IKEDA, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (07): : 987 - 990
[10] PLASTIC CRYSTALS - A HISTORICAL REVIEW
TIMMERMANS, J
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1961, 18 (01) : 1 - 8

← 1 →