A new approach to the synthesis of carbon chains capped by metal clusters

被引：57

作者：

Bruce, MI ^{[1
]}

Smith, ME

Zaitseva, NN

Skelton, BW

White, AH

机构：

[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

[2] Univ Western Australia, Dept Chem, Crawley, WA 6009, Australia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 670卷 / 1-2期

基金：

澳大利亚研究理事会;

关键词：

carbon chains; cobalt clusters; capped clusters; C-10; chains;

D O I：

10.1016/S0022-328X(02)02186-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions Of Co-3(mu(3)-CBr)(mu-dppm)(CO)(7) with {Au[P(tol)(3)]}(2)[mu-(CdropC)(n)} (n=2-4) have given {Co-3(mu-dppm)(CO)(7)}{mu(3):mu(3)-C(Cdrop C)(n)C} [n = 2 (1), 3 (2), 4 (3)] containing carbon chains capped by the cobalt clusters. Tetracyanoethene reacts with 2 to give {Co-3(mu-dppM)(CO)(7)}(2){mu(3):mu(3)-C(CdropC)(2)C[=C(CN)(2)]C[=C(CN)(2)]C} (4). X-ray structural characterisation of 1, 3 and 4 are reported, that for 3 being the first of a cluster-capped C-10 chain. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：170 / 177

页数：8

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