Preparation and structures of {Li[C(N,tBu)2(HN,tBu)]}2.(THF) and {Li2[C(N,tBu)3]}2, containing the novel anions [C(N,tBu)2(HN,tBu)]- and [C(N,tBu)3]2-

被引：47

作者：

Chivers, T ^{[1
]}

Parvez, M ^{[1
]}

Schatte, G ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 550卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

hetero-trimethylenemethane ligands; C-N-Li cluster; carbodiimides; X-ray structure;

D O I：

10.1016/S0022-328X(97)00182-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of tert-butyl carbodiimide with one equivalent of (LiNHBu)-Bu-t in tetrahydrofuran at -78 degrees C produces {Li[C((NBu)-Bu-t)(2)((HNBu)-Bu-t)]}(2) .(THF) (1), which is an eight-membered Li2C2N4 ring; the deprotonation of 1 with two equivalents of n-BuLi in tetrahydrofuran at -78 degrees C and recrystallization of the product from n-pentane yielded the unsolvated dimer {Li-2[C((NBu)-Bu-t)(3)]}(2) (2), which has a distorted cyclic ladder structure. (C) 1998 Elsevier Science S.A.

引用

页码：213 / 220

页数：8

共 26 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS
ALLEN, FH
KENNARD, O
WATSON, DG
BRAMMER, L
ORPEN, AG
TAYLOR, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12): : S1 - S19
[2] ALTOMARE A, UNPUB
[3] THE LADDERING PRINCIPLE IN LITHIUM AMIDE CHEMISTRY - THE CRYSTAL AND MOLECULAR-STRUCTURE OF THE PYRROLIDIDOLITHIUM ADDUCT [H2C(CH2)3NLI]3.MEN(CH2CH2NME2)2
ARMSTRONG, DR
BARR, D
CLEGG, W
MULVEY, RE
REED, D
SNAITH, R
WADE, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (11) : 869 - 870
[4] Synthesis and structure of [{(Me(3)Si)(2)N}(2)Cd{(PhN)(3)C}Li-2 center dot 3thf]; An unusual heterobimetallic co-complex containing three different metal coordination environments
Bailey, PJ
Mitchell, LA
Raithby, PR
Rennie, MA
Verhorevoort, K
Wright, DS
[J]. CHEMICAL COMMUNICATIONS, 1996, (11) : 1351 - 1352
[5] THE FIRST TRIAZATRIMETHYLENEMETHANE DIANION - CRYSTAL-STRUCTURE OF DILITHIO-TRIPHENYLGUANIDINE LI-2[C(NPH)(3)] AS ITS TETRAHYDROFURAN SOLVATE
BAILEY, PJ
BLAKE, AJ
KRYSZCZUK, M
PARSONS, S
REED, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) : 1647 - 1648
[6] Novel octameric structure of the lithium primary amide [{Bu(t)N(H)Li}(8)] and its implication for the directed synthesis of heterometallic imide cages
Barnett, NDR
Clegg, W
Horsburgh, L
Lindsay, DM
Liu, QY
Mackenzie, FM
Mulvey, RE
Williard, PG
[J]. CHEMICAL COMMUNICATIONS, 1996, (20) : 2321 - 2322
[7] BEURSKENS PT, 1994, DIRFIX 94 PROGRAM SY
[8] Preparation and structure of [Li2Se(N(t)Bu)(3)](2), containing the novel Se(N(t)Bu)(3)(2-) anion
Chivers, T
Parvez, M
Schatte, G
[J]. INORGANIC CHEMISTRY, 1996, 35 (14) : 4094 - +
[9] Pyramidal tellurite ions Te(N(t)Bu)(2)(E(t)Bu)(-)(E=0,NH): Syntheses and structures of [K(THF)Te(N(t)Bu)(2)(O(t)Bu)](2) and {[LiTe(N(t)Bu)(2)(NH(t)Bu)]2LiCl}(2)
Chivers, T
Gao, XL
Parvez, M
[J]. INORGANIC CHEMISTRY, 1996, 35 (03) : 553 - &
[10] Investigations of the TeCl4-(t)BuNHLi reaction: Synthesis, X-ray structures, and fluxional behavior of the tellurium-nitrogen compounds [Li2Te(N(t)Bu)(3)](2), {[LiTe(N(t)Bu)(2)(NH(t)Bu)]2LiCl}(2), and {Te-2(N(t)Bu)(4)[LiTe(N(t)Bu)(2)(NH(t)Bu)]LiCl}(2)
Chivers, T
Gao, XL
Parvez, M
[J]. INORGANIC CHEMISTRY, 1996, 35 (15) : 4336 - 4341

← 1 2 3 →