Strategies for laser-induced fluorescence detection of nitric oxide in high-pressure flames.: II.: A-X(0,1) excitation

被引:35
作者
Bessler, WG
Schulz, C
Lee, T
Jeffries, JB
Hanson, RK
机构
[1] Heidelberg Univ, Inst Chem Phys, D-69120 Heidelberg, Germany
[2] Stanford Univ, Dept Mech Engn, High Temp Gasdynam Lab, Stanford, CA 94305 USA
关键词
D O I
10.1364/AO.42.002031
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A-X(0,1) excitation is a promising new approach for NO laser-induced fluorescence (LIF) diagnostics at elevated pressures and temperatures. We present what to our knowledge are the first detailed spectroscopic investigations within this excitation band using wavelength-resolved LIF measurements in premixed methane/air flames at pressures between 1 and 60 bar and a range of fuel/air ratios. Interference from O-2 LIF is a significant problem in lean flames for NO LIF measurements, and pressure broadening and quenching lead to increased interference with increased pressure. Three different excitation schemes are identified that maximize NO/O-2 LIF signal ratios, thereby minimizing the O-2 interference. The NO LIF signal strength, interference by hot molecular oxygen, and temperature dependence of the three schemes are investigated. (C) 2003 Optical Society of America.
引用
收藏
页码:2031 / 2042
页数:12
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