Aqua(2,2′-bipyridine)(2,2′:6′,2"-terpyridine)-ruthenium(II) bis(perchlorate)

被引：7

作者：

Qvortrup, Katrine

McKenzie, Christine J.

Bond, Andrew D.

机构：

[1] Univ So Denmark, Dept Chem & Phys, Odense 5230, Denmark

[2] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

single-crystal X-ray study; T=180 K; Mean sigma(C-C)=0.007 angstrom; Disorder in solvent or counterion; R factor=0.043; wR factor=0.117; data-to-parameter ratio=13.5;

D O I：

10.1107/S1600536807015504

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Ru(C10H8N2)(C15H11N3)(H2O)](ClO4)(2), two pairs of hydrogen bonds between the coordinated water molecules and perchlorate anions link the complexes into discrete {[(bipy)(terpy)Ru2O)](ClO4)(2)}(2) units (bipy = 2,2'-bipyridine and terpy = 2,2': 6',2''-terpyridine).

引用

页码：M1400 / M1401

页数：2

共 8 条

[1]

BRUKER, 2003, SAINT VERSION 7 06A

[2]

BRUKER, 2000, SHELXTL VERSION 6 10

[3]

BRUKERNONIUS, 2004, APEX2 VERSION 1 0 22

[4] RU(II) POLYPYRIDINE COMPLEXES - PHOTOPHYSICS, PHOTOCHEMISTRY, ELECTROCHEMISTRY, AND CHEMI-LUMINESCENCE [J].