Extended corresponding-states behavior for particles with variable range attractions

被引：408

作者：

Noro, MG ^{[1
]}

Frenkel, D ^{[1
]}

机构：

[1] FOM, Inst Atom & Mol Phys, NL-1098 SJ Amsterdam, Netherlands

来源：

JOURNAL OF CHEMICAL PHYSICS | 2000年 / 113卷 / 08期

关键词：

D O I：

10.1063/1.1288684

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We propose an extension of the law of corresponding states that can be applied to systems-such as colloidal suspensions-that have widely different ranges of attractive interactions. We argue that the "reduced" second virial coefficient is a convenient parameter to quantify the effective range of attraction. Knowledge of the pair-potential alone allows one to estimate the relative location of the liquid-vapor and solid-fluid coexistence curves. (C) 2000 American Institute of Physics. [S0021-9606(00)52432-5].

引用

页码：2941 / 2944

页数：4

共 30 条

[1]

ANDERSEN HC, 1971, PHYS REV A, V4, P1579

[2] Phase diagram of colloidal solutions [J].

Asherie, N ;

Lomakin, A ;

Benedek, GB .

PHYSICAL REVIEW LETTERS, 1996, 77 (23) :4832-4835

[3] WHAT IS LIQUID - UNDERSTANDING STATES OF MATTER [J].

BARKER, JA ;

HENDERSON, D .

REVIEWS OF MODERN PHYSICS, 1976, 48 (04) :587-671

[4]

BAXTER RJ, 1968, J CHEM PHYS, V49, P2270

[5] A COMPLETELY ANALYTIC PERTURBATION-THEORY FOR THE SQUARE-WELL FLUID OF VARIABLE WELL WIDTH [J].

CHANG, J ;

SANDLER, SI .

MOLECULAR PHYSICS, 1994, 81 (03) :745-765

[6] SOLUTIONS OF THE YVON-BORN-GREEN EQUATION FOR A SYSTEM OF SQUARE-WELL MOLECULES AT A TEMPERATURE BELOW THE TRIPLE POINT [J].

CO, KU ;

LUKS, KD ;

KOZAK, JJ .

MOLECULAR PHYSICS, 1978, 36 (06) :1883-1896

[7] VAN-DER-WAALS THEORY FOR SOLIDS [J].

DAANOUN, A ;

TEJERO, CF ;

BAUS, M .

PHYSICAL REVIEW E, 1994, 50 (04) :2913-2924

[8] Direct simulation of the phase behavior of binary hard-sphere mixtures: Test of the depletion potential description [J].

Dijkstra, M ;

van Roij, R ;

Evans, R .

PHYSICAL REVIEW LETTERS, 1999, 82 (01) :117-120

[9] Phase diagram of highly asymmetric binary hard-sphere mixtures [J].

Dijkstra, M ;

van Roij, R ;

Evans, R .

PHYSICAL REVIEW E, 1999, 59 (05) :5744-5771

[10] Vapor-liquid equilibria of square-well spheres [J].

Elliott, JR ;

Hu, LG .

JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (06) :3043-3048

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