Redox-active porous metal-organic framework producing silver nanoparticles from AgI ions at room temperature

被引：260

作者：

Moon, HR ^{[1
]}

Kim, JH ^{[1
]}

Suh, MP ^{[1
]}

机构：

[1] Seoul Natl Univ, Sch Chem, Seoul 151747, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 08期

关键词：

coordination polymers; host-guest systems; microporous materials; nanostructures; silver;

D O I：

10.1002/anie.200461408

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hi ho silver! Coordination polymer chains assembled from a NiII hexaazamacrocycle and sodium 4,4′-biphenyldicarboxylate can be packed to form a porous framework (see picture). Nanocomposites of silver particles and matrix can be prepared by immersing the framework in AgNO3 solution, and the matrix-free silver nanoparticles (≈3 nm) isolated by treatment of the solid with boiling dioctyl ether containing oleic acid. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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页码：1261 / 1265

页数：5

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