CuO nanodendrites synthesized by a novel hydrothermal route

被引:126
作者
Li, SZ [1 ]
Zhang, H [1 ]
Ji, YJ [1 ]
Yang, DR [1 ]
机构
[1] Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
关键词
D O I
10.1088/0957-4484/15/11/007
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
CuO nanodendrites have been synthesized by a simple and novel hydrothermal method. Their morphology, structure, and composition have been also characterized. The results show that an as-prepared nanodendrite is composed of a main branch-like nanorod near upon a micrometre in length and about 100 nm in diameter and the sub-branch nanorods several hundred nanometres in length and 20-60 nm in diameter. The dendrite-like CuO nanostructures are of monoclinic phase and single crystalline in nature. The investigation of the hydrothermal process assisted by different quantities of ethylene glycol (EG) indicates that EG plays a critical role in the formation of dendrite-like CuO nanostructures. A possible mechanism for the formation of such CuO nanostructures is discussed. Furthermore, the correlation between the optical spectrum and the different morphologies of copper oxides nanomaterials is also discussed.
引用
收藏
页码:1428 / 1432
页数:5
相关论文
共 28 条
[1]   Synthesis and properties of Cu2O quantum particles [J].
Borgohain, K ;
Murase, N ;
Mahamuni, S .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (03) :1292-1297
[2]   Growth of hex-pod-like Cu2O whisker under hydrothermal conditions [J].
Chen, ZZ ;
Shi, EW ;
Zheng, YQ ;
Li, WJ ;
Xiao, B ;
Zhuang, JY .
JOURNAL OF CRYSTAL GROWTH, 2003, 249 (1-2) :294-300
[3]   Resonance as a measure of pairing correlations in the high-Tc superconductor YBa2Cu3O6.6 [J].
Dai, PC ;
Mook, HA ;
Aeppli, G ;
Hayden, SM ;
Dogan, F .
NATURE, 2000, 406 (6799) :965-968
[4]   Growth and structure evolution of novel tin oxide diskettes [J].
Dai, ZR ;
Pan, ZW ;
Wang, ZL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (29) :8673-8680
[5]  
Deng JF, 1996, APPL CATAL A-GEN, V139, P75
[6]   CuO catalytic membrane as selectivity trimmer for metal oxide gas sensors [J].
Frietsch, M ;
Zudock, F ;
Goschnick, J ;
Bruns, M .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 65 (1-3) :379-381
[7]   Magnetic resonant mode in the single-layer high-temperature superconductor Tl2Ba2CuO6+δ [J].
He, H ;
Bourges, P ;
Sidis, Y ;
Ulrich, C ;
Regnault, LP ;
Pailhès, S ;
Berzigiarova, NS ;
Kolesnikov, NN ;
Keimer, B .
SCIENCE, 2002, 295 (5557) :1045-1047
[8]   Star-shaped PbS crystals fabricated by a novel hydrothermal method [J].
Ji, YJ ;
Ma, XY ;
Zhang, H ;
Xu, J ;
Yang, D .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (44) :7611-7615
[9]   Single-crystalline SnS2 nano-belts fabricated by a novel hydrothermal method [J].
Ji, YJ ;
Zhang, H ;
Ma, XY ;
Xu, J ;
Yang, D .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (44) :L661-L665
[10]   CuO nanowires can be synthesized by heating copper substrates in air [J].
Jiang, XC ;
Herricks, T ;
Xia, YN .
NANO LETTERS, 2002, 2 (12) :1333-1338