Performance evaluation of poly(N-methylaniline) and polyisothianaphthene in charge-storage devices

被引:55
作者
Sivakkumar, SR [1 ]
Saraswathi, R [1 ]
机构
[1] Madurai Kamaraj Univ, Dept Mat Sci, Madurai 625021, Tamil Nadu, India
关键词
poly(N-methylaniline); polyisothianaphthene; conducting polymer batteries; polymeric supercapacitors;
D O I
10.1016/j.jpowsour.2004.05.060
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The charge-discharge characteristics of Li/poly(N-methylaniline) (PNMA) coin cells with an ethylenecarbonate-dimethylcarbonate mixture containing 1 M LiCIO4 as electrolyte are studied. The PNMA is modified from a p-doped polymer to a self-doped polymer by a simple sulfonation procedure and its performance in a rechargeable cell is evaluated. Parallel experiments on polyaniline and sulfonated polyaniline are also performed. The application of the low band-gap polymer polyisothianaphthene (PITN) in a non-aqueous rechargeable cell and also in a capacitor is studied. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:322 / 328
页数:7
相关论文
共 47 条
[1]  
[Anonymous], SYNTH MET
[2]   Polymer-based redox supercapacitors: A comparative study [J].
Arbizzani, C ;
Mastragostino, M ;
Meneghello, L .
ELECTROCHIMICA ACTA, 1996, 41 (01) :21-26
[3]   SULFONATED POLYANILINE FILMS AS CATION INSERTION ELECTRODES FOR BATTERY APPLICATIONS .1. STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION [J].
BARBERO, C ;
MIRAS, MC ;
SCHNYDER, B ;
HAAS, O ;
KOTZ, R .
JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (12) :1775-1783
[4]   ALTERATION OF THE ION-EXCHANGE MECHANISM OF AN ELECTROACTIVE POLYMER BY MANIPULATION OF THE ACTIVE-SITE - PROBE BEAM DEFLECTION AND QUARTZ CRYSTAL MICROBALANCE STUDY OF POLY(ANILINE) AND POLY(N-METHYLANILINE) [J].
BARBERO, C ;
MIRAS, MC ;
HAAS, O ;
KOTZ, R .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 310 (1-2) :437-443
[5]   Sulphonated polyaniline (SPAN) films as cation insertion electrodes for battery applications - Part II: Exchange of mobile species in aqueous and non-aqueous solutions [J].
Barbero, C ;
Miras, MC ;
Kotz, R ;
Haas, O .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 437 (1-2) :191-198
[6]   SIMPLE SYNTHETIC ROUTE TO BENZO[C]THIOPHENE AND NAPHTHO[C]THIOPHENES [J].
CAVA, MP ;
POLLACK, NM ;
MAMER, OA ;
MITCHELL, MJ .
JOURNAL OF ORGANIC CHEMISTRY, 1971, 36 (25) :3932-&
[7]   WATER-SOLUBLE SELF-ACID-DOPED CONDUCTING POLYANILINE - STRUCTURE AND PROPERTIES [J].
CHEN, SA ;
HWANG, GW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (40) :10055-10062
[8]   Structure characterization of self-acid-doped sulfonic acid ring-substituted polyaniline in its aqueous solutions and as solid film [J].
Chen, SA ;
Hwang, GW .
MACROMOLECULES, 1996, 29 (11) :3950-3955
[9]   Structures and properties of the water-soluble self-acid-doped conducting polymer blends: Sulfonic acid ring-substituted polyaniline/poly(vinyl alcohol) and poly(aniline-co-N-propanesulfonic acid aniline)/poly(vinyl alcohol) [J].
Chen, SA ;
Hwang, GW .
POLYMER, 1997, 38 (13) :3333-3346
[10]   Polyaniline-deposited porous carbon electrode for supercapacitor [J].
Chen, WC ;
Wen, TC ;
Teng, HS .
ELECTROCHIMICA ACTA, 2003, 48 (06) :641-649