Enantioselective synthesis of γ-lactones from thioglycolic acid:: Syntheses of (-)-muricatacin and 5-epi-(-)-muricatacin

被引:23
作者
Chang, SW [1 ]
Hung, CY [1 ]
Liu, HH [1 ]
Uang, BJ [1 ]
机构
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan
关键词
D O I
10.1016/S0957-4166(98)00007-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
An approach for the enantioselective synthesis of functionalized gamma-lactones and its application to the syntheses of (-)-muricatacin 1a and 5-epi-(-)-muricatacin 1b is reported. A sequential oxidation of the intermediate 4 with m-chloroperoxybenzoic acid was conducted to realize the reaction mechanism. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:521 / 529
页数:9
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