Hydrogen-bonding-directed layer-by-layer films: Effect of electrostatic interaction on the microporous morphology variation

被引：43

作者：

Bai, SL

Wang, ZQ

Zhang, X ^{[1
]}

Wang, B

机构：

[1] Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China

[2] Jilin Univ, Coll Chem, Key Lab Supramol Struct & Mat, Changchun 130023, Peoples R China

[3] Lamar Univ, Dept Chem & Phys, Beaumont, TX 77710 USA

[4] Lamar Univ, Dept Chem Engn, Beaumont, TX 77710 USA

来源：

LANGMUIR | 2004年 / 20卷 / 26期

关键词：

D O I：

10.1021/la047968j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The effect of electrostatic interaction on the process of the morphology variation were investigated. It was observed that a slight charge in polymer chains has a great effect on the morphological variation. It was suggested that the electrostatic repulsion brought by charge within the polymer can impede the formation of the coil conformation/aggregation of polymer chains. It was reported that a simple and effective method for regulating the process of microporous morphology variation can be developed by employing some degree of charge ratio in polymer chains.

引用

页码：11828 / 11832

页数：5

共 25 条

[1] POLYPYRIDINE COMPLEXES OF RUTHENIUM(II) BOUND TO POLY(4-VINYLPYRIDINE) - SYNTHESIS, CHARACTERIZATION, AND THIN-FILM ELECTROCHEMISTRY OF A SERIES OF BIS(BIPYRIDINE) METALLOPOLYMERS [J].